Ashbrook, S. E. and Berry, A. J. and Hibberson, W. O. and Steuernagel, S. and Wimperis, S. (2005) High-resolution 17O MAS NMR spectroscopy of forsterite ({alpha}-Mg2SiO4), wadsleyite (ß-Mg2SiO4), and ringwoodite ({gamma}-Mg2SiO4). American Mineralogist, 90 (11-12). pp. 1861-1870. DOI https://doi.org/10.2138/am.2005.1915
![]() |
PDF
Ashbrook_S.E._et_al_Am_Mineralogist,90,11-12(2005)_1861-1870.pdf Restricted to Registered users only Download (11MB) |
Abstract
The high sensitivity of the satellite-transition (ST) MAS NMR technique was exploited to obtain high-resolution 17O MAS NMR spectra of the three polymorphs of Mg2SiO4: forsterite ({alpha}-Mg2SiO4), wadsleyite (ß-Mg2SiO4), and ringwoodite ({gamma}-Mg2SiO4). High NMR sensitivity was important in this application because 17O-enriched, Fe-free materials are required for 17O NMR and high-pressure syntheses of the dense ß and {gamma} polymorphs result in a only a few milligrams of these solids. In all, eight distinct O species were identified and assigned: three in forsterite, four in wadsleyite, and one in ringwoodite, in agreement with the number of O sites in their crystal structures. The isotropic chemical shifts extracted are in excellent agreement with a previously published correlation with Si-O bond length. However, unexpectedly large quadrupolar coupling constants were found for the non-bridging O species in the dense polymorphs wadsleyite and ringwoodite.
Item Type: | Article |
---|---|
Additional Information: | Bruker BioSpin GmbH ; cml |
Uncontrolled Keywords: | 2005 AREP 2005 P IA49 |
Subjects: | 03 - Mineral Sciences |
Divisions: | 03 - Mineral Sciences |
Journal or Publication Title: | American Mineralogist |
Volume: | 90 |
Page Range: | pp. 1861-1870 |
Identification Number: | https://doi.org/10.2138/am.2005.1915 |
Depositing User: | Sarah Humbert |
Date Deposited: | 06 Sep 2011 13:38 |
Last Modified: | 23 Jul 2013 09:58 |
URI: | http://eprints.esc.cam.ac.uk/id/eprint/1571 |
Actions (login required)
![]() |
View Item |