A synthesis of marine sediment core &delta;<sup>13</sup>C data over the last 150 000 years

Oliver, K. I. C. and Hoogakker, B. A. A. and Crowhurst, S. and Henderson, G. M. and Rickaby, R. E. M. and Edwards, N. R. and Elderfield, H. (2009) A synthesis of marine sediment core &delta;<sup>13</sup>C data over the last 150 000 years. Climate of the Past Discussions, 5 (6). pp. 2497-2554. ISSN 1814-9359 DOI https://doi.org/10.5194/cpd-5-2497-2009

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Official URL: http://dx.doi.org/10.5194/cpd-5-2497-2009


Abstract. The isotopic composition of carbon, δ13C, in seawater is used in reconstructions of ocean circulation, marine productivity, air-sea gas exchange, and biosphere carbon storage. Here, a synthesis of δ13C measurements taken from foraminifera in marine sediment cores over the last 150 000 years is presented. The dataset comprises previously published and unpublished data from benthic and planktonic records throughout the global ocean. Data are placed on a common δ18O age scale and filtered to remove timescales shorter than 6 kyr. Error estimates account for the resolution and scatter of the original data, and uncertainty in the relationship between δ13C of calcite and of dissolved inorganic carbon (DIC) in seawater. This will assist comparison with δ13C of DIC output from models, which can be further improved using model outputs such as temperature, DIC concentration, and alkalinity to improve estimates of fractionation during calcite formation. High global deep ocean δ13C, indicating isotopically heavy carbon, is obtained during Marine Isotope Stages (MIS) 1, 3, 5a, 5c and 5e, and low δ13C during MIS 2, 4 and 6, which are temperature minima, with larger amplitude variability in the Atlantic Ocean than the Pacific Ocean. This is likely to result from changes in biosphere carbon storage, modulated by changes in ocean circulation, productivity, and air-sea gas exchange. The North Atlantic vertical δ13C gradient is greater during temperature minima than temperature maxima, attributed to changes in the spatial extent of Atlantic source waters. There are insufficient data from shallower than 2500 m to obtain a coherent pattern in other ocean basins. The data synthesis indicates that basin-scale δ13C during the last interglacial (MIS 5e) is not clearly distinguishable from the Holocene (MIS 1) or from MIS 5a and 5c, despite significant differences in ice volume and atmospheric CO2 concentration during these intervals. Similarly, MIS 6 is only distinguishable from MIS 2 or 4 due to globally lower δ13C values both in benthic and planktonic data. This result is obtained despite individual records showing differences between these intervals, indicating that care must be used in interpreting large scale signals from a small number of records.

Item Type: Article
Uncontrolled Keywords: 2010AREP; IA61;
Subjects: 01 - Climate Change and Earth-Ocean Atmosphere Systems
Divisions: 01 - Climate Change and Earth-Ocean Atmosphere Systems
Journal or Publication Title: Climate of the Past Discussions
Volume: 5
Page Range: pp. 2497-2554
Identification Number: https://doi.org/10.5194/cpd-5-2497-2009
Depositing User: Sarah Humbert
Date Deposited: 10 Sep 2010 16:21
Last Modified: 23 Jul 2013 10:00
URI: http://eprints.esc.cam.ac.uk/id/eprint/1936

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