Controls on the tropospheric oxidizing capacity during an idealized Dansgaard-Oeschger event, and their implications for the rapid rises in atmospheric methane during the last glacial period

Levine, J. G. and Wolff, E. W. and Hopcroft, P. O. and Valdes, P. J. (2012) Controls on the tropospheric oxidizing capacity during an idealized Dansgaard-Oeschger event, and their implications for the rapid rises in atmospheric methane during the last glacial period. Geophysical Research Letters, 39. L12805. ISSN 0094–8276 DOI 10.1029/2012GL051866

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Abstract

The ice core record reveals large variations in the concentration of atmospheric methane, CH4, over the last 800 kyr. Amongst the most striking natural features are the large, rapid rises in CH4, of 100-200 ppbv, on timescales of less than 100 years, at the beginning of Dansgaard-Oeschger (D-O) events during the last glacial period (21-110 kyr before present). Despite the potential insight they could offer into the likelihood of future rapid rises in CH4, the relative roles of changes in methane sources and sinks during D-O events have been little explored. Here, we use a global atmospheric chemistry-transport model to explore-for the first time, in a process-based fashion-controls on the oxidizing capacity during an idealized D-O event that features a characteristically rapid rise in CH4. We find that the two controls previously identified in the literature as having had significant (though opposing) influences on the oxidizing capacity between glacial and interglacial periods-changes in air temperature and emissions of non-methane volatile organic compounds from vegetation-offset one another between idealized Heinrich stadial and Greenland interstadial states. The result is, the net change in oxidizing capacity is very small, implying the rapid rises in CH4 at the beginning of D-O events were almost entirely source-driven. This poses a challenge to earth-system models-to generate a sufficiently large increase in methane emissions in response to a simulated D-O event, via a more realistic freshwater forcing impacting the strength of the Atlantic meridional overturning circulation or, possibly, other climate-change mechanisms. Citation: Levine, J. G., E. W. Wolff, P. O. Hopcroft, and P. J. Valdes (2012), Controls on the tropospheric oxidizing capacity during an idealized Dansgaard-Oeschger event, and their implications for the rapid rises in atmospheric methane during the last glacial period, Geophys. Res. Lett., 39, L12805, doi:10.1029/2012GL051866.

Item Type:	Article
Additional Information:	©2012. American Geophysical Union. All Rights Reserved.
Uncontrolled Keywords:	NIL AREP
Subjects:	01 - Climate Change and Earth-Ocean Atmosphere Systems
Divisions:	01 - Climate Change and Earth-Ocean Atmosphere Systems
Journal or Publication Title:	Geophysical Research Letters
Volume:	39
Page Range:	L12805
Identification Number:	10.1029/2012GL051866
Depositing User:	Sarah Humbert
Date Deposited:	31 Aug 2013 14:35
Last Modified:	31 Aug 2013 14:35
URI:	http://eprints.esc.cam.ac.uk/id/eprint/2846

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