Direct visualisation of carbon dioxide adsorption in gate-opening zeolitic imidazolate framework ZIF-7

Zhao, Pu and Lampronti, Giulio I. and Lloyd, Gareth O. and Suard, Emmanuelle and Redfern, Simon A. T. (2013) Direct visualisation of carbon dioxide adsorption in gate-opening zeolitic imidazolate framework ZIF-7. Journal of Materials Chemistry A, 2 (3). pp. 620-623. DOI https://doi.org/10.1039/C3TA13981F

Preview	Image GA.gif - Published Version Download (18kB) | Preview
Preview	Text c3ta13981f.pdf - Published Version Available under License Creative Commons Attribution. Download (422kB) | Preview
	Text c3ta13981f.txt - Supplemental Material Download (16kB)
Preview	Text c3ta13981f_ sup.pdf - Supplemental Material Download (923kB) | Preview

Abstract

The crystal structures of zeolitic imidazolate framework 7 (ZIF-7) under various CO2 pressures were studied by high-resolution neutron powder diffraction. CO2 adsorption in ZIF-7 is visualised and demonstrated to be primarily controlled by the benzimidazolate ligands via a gate-opening mechanism. Our results highlight the importance of pressure on the CO2 adsorption and the related structural framework responses in ZIF-7.

Item Type:	Article
Uncontrolled Keywords:	2013AREP; IA67; Phd., OA;
Subjects:	03 - Mineral Sciences
Divisions:	03 - Mineral Sciences 07 - Gold Open Access
Journal or Publication Title:	Journal of Materials Chemistry A
Volume:	2
Page Range:	pp. 620-623
Identification Number:	https://doi.org/10.1039/C3TA13981F
Depositing User:	Sarah Humbert
Date Deposited:	21 Mar 2014 17:59
Last Modified:	13 Jul 2014 21:19
URI:	http://eprints.esc.cam.ac.uk/id/eprint/3000

Actions (login required)

View Item