Direct visualisation of carbon dioxide adsorption in gate-opening zeolitic imidazolate framework ZIF-7

Zhao, Pu and Lampronti, Giulio I. and Lloyd, Gareth O. and Suard, Emmanuelle and Redfern, Simon A. T. (2013) Direct visualisation of carbon dioxide adsorption in gate-opening zeolitic imidazolate framework ZIF-7. Journal of Materials Chemistry A, 2 (3). pp. 620-623. DOI 10.1039/C3TA13981F

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...

Abstract

The crystal structures of zeolitic imidazolate framework 7 (ZIF-7) under various CO2 pressures were studied by high-resolution neutron powder diffraction. CO2 adsorption in ZIF-7 is visualised and demonstrated to be primarily controlled by the benzimidazolate ligands via a gate-opening mechanism. Our results highlight the importance of pressure on the CO2 adsorption and the related structural framework responses in ZIF-7.

Item Type: Article
Uncontrolled Keywords: 2013AREP; IA67; Phd., OA;
Subjects: 03 - Mineral Sciences
Divisions: 03 - Mineral Sciences
07 - Gold Open Access
Journal or Publication Title: Journal of Materials Chemistry A
Volume: 2
Page Range: pp. 620-623
Identification Number: 10.1039/C3TA13981F
Depositing User: Sarah Humbert
Date Deposited: 21 Mar 2014 17:59
Last Modified: 13 Jul 2014 21:19
URI: http://eprints.esc.cam.ac.uk/id/eprint/3000

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