Zhao, Pu and Lampronti, Giulio I. and Lloyd, Gareth O. and Suard, Emmanuelle and Redfern, Simon A. T. (2013) Direct visualisation of carbon dioxide adsorption in gate-opening zeolitic imidazolate framework ZIF-7. Journal of Materials Chemistry A, 2 (3). pp. 620-623. DOI https://doi.org/10.1039/C3TA13981F
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Abstract
The crystal structures of zeolitic imidazolate framework 7 (ZIF-7) under various CO2 pressures were studied by high-resolution neutron powder diffraction. CO2 adsorption in ZIF-7 is visualised and demonstrated to be primarily controlled by the benzimidazolate ligands via a gate-opening mechanism. Our results highlight the importance of pressure on the CO2 adsorption and the related structural framework responses in ZIF-7.
Item Type: | Article |
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Uncontrolled Keywords: | 2013AREP; IA67; Phd., OA; |
Subjects: | 03 - Mineral Sciences |
Divisions: | 03 - Mineral Sciences 07 - Gold Open Access |
Journal or Publication Title: | Journal of Materials Chemistry A |
Volume: | 2 |
Page Range: | pp. 620-623 |
Identification Number: | https://doi.org/10.1039/C3TA13981F |
Depositing User: | Sarah Humbert |
Date Deposited: | 21 Mar 2014 17:59 |
Last Modified: | 13 Jul 2014 21:19 |
URI: | http://eprints.esc.cam.ac.uk/id/eprint/3000 |
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