Uranium and barium cycling in a salt wedge subterranean estuary: The influence of tidal pumping

Santos, Isaac R. and Burnett, William C. and Misra, Sambuddha and Suryaputra, I.G.N.A and Chanton, Jeffrey P. and Dittmar, Thorsten and Peterson, Richard N. (2011) Uranium and barium cycling in a salt wedge subterranean estuary: The influence of tidal pumping. Chemical Geology, 287 (1-2). pp. 114-123. DOI https://doi.org/10.1016/j.chemgeo.2011.06.005

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Official URL: http://dx.doi.org/10.1016/j.chemgeo.2011.06.005


The contribution of submarine groundwater discharge (SGD) to oceanic metal budgets is only beginning to be explored. Here, we demonstrate that biogeochemical processes in a northern Florida subterranean estuary (STE) significantly alter U and Ba concentrations entering the coastal ocean via SGD. Tidal pumping controlled the distribution of dissolved metals in shallow beach groundwater. Hourly observations of intertidal groundwaters revealed high U and low Ba concentrations at high tide as a result of seawater infiltration into the coastal aquifer. During ebb tide, U decreased and Ba increased due to freshwater dilution and, more importantly, biogeochemical reactions that removed U and added Ba to solution. U removal was apparently a result of precipitation following the reduction of U(VI) to U(IV). A significant correlation between Ba and dissolved organic carbon (DOC) in shallow beach groundwaters implied a common source, likely the mineralization of marine particulate organic matter driven into the beach face by tidal pumping. In deeper groundwaters, where the labile organic matter had been depleted, Ba correlated with Mn. We estimate that net SGD fluxes were -163 and +1660μmolm-1d-1 for U and Ba, respectively (or -1 and +8μmolm-2d-1 if a 200-m wide seepage area is considered). Our results support the emerging concept that subterranean estuaries are natural biogeochemical reactors where metal concentrations are altered relative to conservative mixing between terrestrial and marine endmembers. These deviations from conservative mixing significantly influence SGD-derived trace metal fluxes. © 2011 Elsevier B.V.

Item Type: Article
Uncontrolled Keywords: NIL AREP
Subjects: 01 - Climate Change and Earth-Ocean Atmosphere Systems
Divisions: 01 - Climate Change and Earth-Ocean Atmosphere Systems
Journal or Publication Title: Chemical Geology
Volume: 287
Page Range: pp. 114-123
Identification Number: https://doi.org/10.1016/j.chemgeo.2011.06.005
Depositing User: Sarah Humbert
Date Deposited: 16 May 2014 11:35
Last Modified: 16 May 2014 11:35
URI: http://eprints.esc.cam.ac.uk/id/eprint/3050

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