Argentophilicity-Dependent Colossal Thermal Expansion in Extended Prussian Blue Analogues

Goodwin, A. L. and Keen, D. A. and Tucker, M. G. and Dove, M. T. and Peters, L. and Evans, J. S. O. (2008) Argentophilicity-Dependent Colossal Thermal Expansion in Extended Prussian Blue Analogues. Journal of the American Chemical Society, 130 (30). pp. 9660-9661. DOI 10.1021/ja803623u

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Abstract

Argentophilicity-Dependent Colossal Thermal Expansion in Extended Prussian Blue Analogues ... Representations of the crystal structure of the A3[M(CN)6] extended Prussian blue framework (a) and the contraction along the trigonal axis toward the ideal cubic framework (b) effected by expansion of the Kagome Ag/D lattices (c). ... (12) The contrasting behavior of 3 relative to that of Ag-containing analogues 1 and 2 is a strong indication that some property of the Ag atoms is responsible for the colossal thermal expansion effects. ...

Item Type: Article
Uncontrolled Keywords: 08AREP IA56 2008 P
Subjects: 03 - Mineral Sciences
Divisions: 03 - Mineral Sciences
Journal or Publication Title: Journal of the American Chemical Society
Volume: 130
Page Range: pp. 9660-9661
Identification Number: 10.1021/ja803623u
Depositing User: Sarah Humbert
Date Deposited: 16 Feb 2009 13:02
Last Modified: 23 Jul 2013 10:07
URI: http://eprints.esc.cam.ac.uk/id/eprint/326

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