Braga, Dario and Grepioni, Fabrizia and Lampronti, Giulio I. (2011) Supramolecular metathesis: co-former exchange in co-crystals of pyrazine with (R, R)-,(S, S)-,(R, S)-and (S, S/R, R)-tartaric acid. CrystEngComm, 13 (9). pp. 3122-3124. ISSN 1466-8033 DOI https://doi.org/10.1039/C0CE00576B
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Abstract
Co-crystals of dextro-(R,R), levo-(S,S), meso-(R,S) and racemic (R,R–S,S)-tartaric acid with pyrazine were obtained by manual kneading and slurry experiments; subsequent reactions in the solid state between these co-crystals and the various forms of tartaric acid in the solid state and via slurry show that co-former exchange takes place according to the sequence of stability [(R,S)-ta]2·py > (S,S/R,R)-ta·py > (R,R)-ta·py or (S,S)-ta·py.
Item Type: | Article |
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Uncontrolled Keywords: | NILAREP |
Subjects: | 03 - Mineral Sciences |
Divisions: | 03 - Mineral Sciences 99 - Other |
Journal or Publication Title: | CrystEngComm |
Volume: | 13 |
Page Range: | pp. 3122-3124 |
Identification Number: | https://doi.org/10.1039/C0CE00576B |
Depositing User: | Giulio Isacco Lampronti |
Date Deposited: | 14 Aug 2015 17:10 |
Last Modified: | 14 Aug 2015 17:10 |
URI: | http://eprints.esc.cam.ac.uk/id/eprint/3438 |
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