Mechanical Preparation of Crystalline Materials. An Oxymoron?

Braga, Dario and Dichiarante, Elena and Grepioni, Fabrizia and Lampronti, Giulio I. and Maini, Lucia and Mazzeo, Paolo P and D'Agostino, Simone (2012) Mechanical Preparation of Crystalline Materials. An Oxymoron? In: Supramolecular Chemistry: From Molecules to Nanomaterials. Wiley Online Library. ISBN 978-0-470-74640-0 Online ISBN: 9780470661345

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/9780470...

Abstract

The thesis developed in this chapter is that reactions taking place between molecular materials (intersolid) or within a molecular material (intrasolid) can be used to produce new crystalline materials in solvent-free conditions and often with quantitative yields. The most common approach to intersolid and, to lesser extent, intrasolid processes is based on the mechanical cogrinding of the solid reactants, which implies comminution of the reactants. The implicit consequence of this is the lack of crystals of the product suitable for single-crystal X-ray diffraction. The mechanical process yields a polycrystalline or amorphous product, with structure and composition that often differ from that obtained from solution crystallization.

Item Type: Book Section
Uncontrolled Keywords: NILAREP
Subjects: 03 - Mineral Sciences
Divisions: 03 - Mineral Sciences
99 - Other
Journal or Publication Title: Supramolecular Chemistry: From Molecules to Nanomaterials
Identification Number: 10.1002/9780470661345.smc115
Depositing User: Giulio Isacco Lampronti
Date Deposited: 20 Aug 2015 15:21
Last Modified: 20 Aug 2015 15:21
URI: http://eprints.esc.cam.ac.uk/id/eprint/3451

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