Determination of the Mg/Mn ratio in foraminiferal coatings: An approach to correct Mg/Ca temperatures for Mn-rich contaminant phases

Hasenfratz, Adam P. and Martínez-García, Alfredo and Jaccard, Samuel L. and Vance, Derek and Wälle, Markus and Greaves, Mervyn and Haug, Gerald H. (2017) Determination of the Mg/Mn ratio in foraminiferal coatings: An approach to correct Mg/Ca temperatures for Mn-rich contaminant phases. Earth and Planetary Science Letters, 457. pp. 335-347. ISSN 0012-821X DOI https://doi.org/10.1016/j.epsl.2016.10.004

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Abstract

The occurrence of manganese-rich coatings on foraminifera can have a significant effect on their bulk Mg/Ca ratios thereby biasing seawater temperature reconstructions. The removal of this Mn phase requires a reductive cleaning step, but this has been suggested to preferentially dissolve Mg-rich biogenic carbonate, potentially introducing an analytical bias in paleotemperature estimates. In this study, the geochemical composition of foraminifera tests from Mn-rich sediments from the Antarctic Southern Ocean (ODP Site 1094) was investigated using solution-based and laser ablation ICP-MS in order to determine the amount of Mg incorporated into the coatings. The analysis of planktonic and benthic foraminifera revealed a nearly constant Mg/Mn ratio in the Mn coating of ∼0.2 mol/mol. Consequently, the coating Mg/Mn ratio can be used to correct for the Mg incorporated into the Mn phase by using the down core Mn/Ca values of samples that have not been reductively cleaned. The consistency of the coating Mg/Mn ratio obtained in this study, as well as that found in samples from the Panama Basin, suggests that spatial variation of Mg/Mn in foraminiferal Mn overgrowths may be smaller than expected from Mn nodules and Mn–Ca carbonates. However, a site-specific assessment of the Mg/Mn ratio in foraminiferal coatings is recommended to improve the accuracy of the correction.

Item Type:	Article
Uncontrolled Keywords:	2016AREP; IA70
Subjects:	01 - Climate Change and Earth-Ocean Atmosphere Systems
Divisions:	01 - Climate Change and Earth-Ocean Atmosphere Systems
Journal or Publication Title:	Earth and Planetary Science Letters
Volume:	457
Page Range:	pp. 335-347
Identification Number:	https://doi.org/10.1016/j.epsl.2016.10.004
Depositing User:	Sarah Humbert
Date Deposited:	31 Jul 2017 11:11
Last Modified:	31 Jul 2017 11:11
URI:	http://eprints.esc.cam.ac.uk/id/eprint/4009

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