The behavior of iron and zinc stable isotopes accompanying the subduction of mafic oceanic crust: A case study from Western Alpine ophiolites

Inglis, Edward C. and Debret, Baptiste and Burton, Kevin W. and Millet, Marc-Alban and Pons, Marie-Laure and Dale, Christopher W. and Bouilhol, Pierre and Cooper, Matthew and Nowell, Geoff M. and McCoy-West, Alex J. and Williams, Helen M. (2017) The behavior of iron and zinc stable isotopes accompanying the subduction of mafic oceanic crust: A case study from Western Alpine ophiolites. Geochemistry, Geophysics, Geosystems, 18 (7). pp. 2562-2579. ISSN 1525-2027 DOI 10.1002/2016GC006735

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Official URL: http://doi.org/10.1002/2016GC006735

Abstract

Arc lavas display elevated Fe3+/ΣFe ratios relative to MORB. One mechanism to explain this is the mobilization and transfer of oxidized or oxidizing components from the subducting slab to the mantle wedge. Here we use iron and zinc isotopes, which are fractionated upon complexation by sulfide, chloride, and carbonate ligands, to remark on the chemistry and oxidation state of fluids released during prograde metamorphism of subducted oceanic crust. We present data for metagabbros and metabasalts from the Chenaillet massif, Queyras complex, and the Zermatt-Saas ophiolite (Western European Alps), which have been metamorphosed at typical subduction zone P-T conditions and preserve their prograde metamorphic history. There is no systematic, detectable fractionation of either Fe or Zn isotopes across metamorphic facies, rather the isotope composition of the eclogites overlaps with published data for MORB. The lack of resolvable Fe isotope fractionation with increasing prograde metamorphism likely reflects the mass balance of the system, and in this scenario Fe mobility is not traceable with Fe isotopes. Given that Zn isotopes are fractionated by S-bearing and C-bearing fluids, this suggests that relatively small amounts of Zn are mobilized from the mafic lithologies in within these types of dehydration fluids. Conversely, metagabbros from the Queyras that are in proximity to metasediments display a significant Fe isotope fractionation. The covariation of δ56Fe of these samples with selected fluid mobile elements suggests the infiltration of sediment derived fluids with an isotopically light signature during subduction.

Item Type: Article
Uncontrolled Keywords: 2017AREP; IA73; Sylvia
Subjects: 05 - Petrology - Igneous, Metamorphic and Volcanic Studies
Divisions: 05 - Petrology - Igneous, Metamorphic and Volcanic Studies
07 - Gold Open Access
Journal or Publication Title: Geochemistry, Geophysics, Geosystems
Volume: 18
Page Range: pp. 2562-2579
Identification Number: 10.1002/2016GC006735
Depositing User: Sarah Humbert
Date Deposited: 01 Sep 2017 17:05
Last Modified: 01 Sep 2017 17:05
URI: http://eprints.esc.cam.ac.uk/id/eprint/4051

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