Calcium isotopes as a record of the marine calcium cycle versus carbonate diagenesis during the late Ediacaran

Tostevin, Rosalie and Bradbury, Harold J. and Shields, Graham A. and Wood, Rachel A. and Bowyer, Fred and Penny, Amelia M. and Turchyn, Alexandra V. (2019) Calcium isotopes as a record of the marine calcium cycle versus carbonate diagenesis during the late Ediacaran. Chemical Geology, 529. p. 119319. ISSN 0009-2541 DOI https://doi.org/10.1016/j.chemgeo.2019.119319

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Official URL: https://doi.org/10.1016/j.chemgeo.2019.119319

Abstract

Calcium isotope ratios in ancient carbonate rocks can provide insight into the global marine calcium cycle as well as local conditions during carbonate mineral precipitation and diagenesis. We compare two extraction techniques for the separation of calcium from other ions before δ44Ca analysis, using an automated ion chromatograph and using manual gravity columns. The two techniques produce the same δ44Ca within error (2σ). We present 31 δ44Ca analyses of carbonate rocks from the Nama Group, Namibia, which record a negative shift in δ44Ca of 0.35‰ between ∼550 and ∼547 Ma, from −1.25‰ to −1.60‰, followed by persistently low δ44Ca (−1.48 ± 0.06‰) between ∼547 and 539 Ma. Very low δ44Ca (<−1.5‰) are commonly interpreted to represent the preservation of local aragonite that has recrystallized to calcite under sediment-buffered conditions (where the composition of the diagenetic carbonate product is determined mainly by the original sediments). The shift in δ44Ca across the Nama Group could therefore represent a change from fluid-buffered diagenesis (where the composition of the diagenetic carbonate mineral is determined mainly by the fluid) to sediment-buffered diagenesis. However, this interpretation is not consistent with either potential geochemical indicators of diagenesis (e.g., δ18O), or changes in large-scale fluid-flow as predicted from sequence stratigraphy. We consider alternative interpretations for generating changes in the δ44Ca of ancient carbonate rocks including enhanced continental weathering, increases in evaporite deposition, and changes in the style of dolomitisation.

Item Type: Article
Uncontrolled Keywords: 2019AREP; IA75
Subjects: 01 - Climate Change and Earth-Ocean Atmosphere Systems
Divisions: 01 - Climate Change and Earth-Ocean Atmosphere Systems
Journal or Publication Title: Chemical Geology
Volume: 529
Page Range: p. 119319
Identification Number: https://doi.org/10.1016/j.chemgeo.2019.119319
Depositing User: Sarah Humbert
Date Deposited: 15 Nov 2019 13:40
Last Modified: 19 Nov 2019 11:02
URI: http://eprints.esc.cam.ac.uk/id/eprint/4536

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