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Lillington, Joseph N.P. and Goût, Thomas L. and Harrison, Mike T. and Iwalewa, Tajudeen M. and Farnan, Ian (2021) Assessing the effect of radioactive waste glass dissolution on early-stage radionuclide migration using simplified geological repository Monte Carlo transport models. MRS Advances. ISSN 2059-8521 DOI https://doi.org/10.1557/s43580-021-00009-0
Lillington, Joseph N.P. and Goût, Thomas L. and Harrison, Mike T. and Farnan, Ian (2020) Assessing static glass leaching predictions from large datasets using machine learning. Journal of Non-Crystalline Solids, 546. p. 120276. ISSN 00223093 DOI https://doi.org/10.1016/j.jnoncrysol.2020.120276
Popel, Aleksej J. and Spurgeon, Steven R. and Matthews, Bethany and Olszta, Matthew J and Tan, Beng Thye and Gouder, Thomas and Eloirdi, Rachel and Buck, Edgar C and Farnan, Ian (2020) An Atomic-Scale Understanding of UO2 Surface Evolution During Anoxic Dissolution. ACS Applied Materials & Interfaces. ISSN 1944-8244 DOI https://doi.org/10.1021/acsami.0c09611
Patel, Karishma B. and Schuller, Sophie and Facq, Sébastien P. and Farnan, Ian (2020) Characterisation of immiscibility in calcium borosilicates used for the immobilisation of Mo 6+ under Au‐irradiation. Journal of the American Ceramic Society. ISSN 0002-7820 DOI https://doi.org/10.1111/jace.17637
Gasparrini, Claudia and Rana, Dhan-sham and Le Brun, Niccolò and Horlait, Denis and Markides, Christos N. and Farnan, Ian and Lee, William E. (2020) On the stoichiometry of zirconium carbide. Scientific Reports, 10 (1). ISSN 2045-2322 DOI https://doi.org/10.1038/s41598-020-63037-0
Lillington, Joseph N.P. and Goût, Thomas L. and Harrison, Mike T. and Farnan, Ian (2020) Predicting radioactive waste glass dissolution with machine learning. Journal of Non-Crystalline Solids, 533. p. 119852. ISSN 0022-3093 DOI https://doi.org/10.1016/j.jnoncrysol.2019.119852
Rana, Dhan-sham B. K. and Solvas, Eugenio Zapatas and Lee, William E. and Farnan, Ian (2020) An investigation of the long-range and local structure of sub-stoichiometric zirconium carbide sintered at different temperatures. Scientific Reports, 10 (1). ISSN 2045-2322 DOI https://doi.org/10.1038/s41598-020-59698-6
Iwalewa, Tajudeen M. and Farnan, I. (2019) Coupling Radioactive Waste Glass Dissolution Measurements in Generic Groundwaters With Reactive Transport Modeling of Repository Scenarios. Water Resources Research, 55 (10). pp. 8010-8027. ISSN 1944-7973 DOI https://doi.org/10.1029/2018WR024218
Hindshaw, Ruth S. and Tosca, Rebecca and Goût, Thomas L. and Farnan, Ian and Tosca, Nicholas J. and Tipper, Edward T. (2019) Experimental constraints on Li isotope fractionation during clay formation. Geochimica Et Cosmochimica Acta, 250. pp. 219-237. ISSN 0016-7037 DOI https://doi.org/10.1016/j.gca.2019.02.015
Goût, Thomas L. and Harrison, Mike T. and Farnan, Ian (2019) Impacts of lithium on Magnox waste glass dissolution. Journal of Non-Crystalline Solids, 517. pp. 96-105. ISSN 0022-3093 DOI https://doi.org/10.1016/j.jnoncrysol.2019.04.040
Popel, Aleksej J. and Tan, Beng Thye and Gouder, Thomas and Lampronti, Giulio I. and Day, Jason and Eloirdi, Rachel and Seibert, Alice and Farnan, Ian (2019) Surface alteration evidence for a mechanism of anoxic dissolution of UO2. Applied Surface Science, 464. pp. 376-379. ISSN 0169-4332 DOI https://doi.org/10.1016/j.apsusc.2018.09.094
Tan, Beng Thye and Popel, Aleksej J. and Wilbraham, Richard J. and Day, Jason and Lampronti, Giulio I. and Boxall, Colin and Farnan, Ian (2019) Surface and electrochemical controls on UO2 dissolution under anoxic conditions. Journal of Nuclear Materials, 520. pp. 41-55. ISSN 0022-3115 DOI https://doi.org/10.1016/j.jnucmat.2019.03.047
Patel, Karishma B. and Peuget, Sylvain and Schuller, Sophie and Lampronti, Giulio I. and Facq, Sébastien P. and Grygiel, Clara and Monnet, Isabelle and Farnan, Ian (2018) Discovery of a maximum damage structure for Xe-irradiated borosilicate glass ceramics containing powellite. Journal of Nuclear Materials, 510. pp. 229-242. ISSN 00223115 DOI https://doi.org/10.1016/j.jnucmat.2018.08.012
Maslakov, Konstantin I. and Teterin, Yury A. and Popel, Aleksej J. and Yu. Teterin, Anton and Ivanov, Kirill E. and Kalmykov, Stepan N. and Petrov, Vladimir G. and Petrov, Peter K. and Farnan, Ian (2018) XPS study of ion irradiated and unirradiated CeO 2 bulk and thin film samples. Applied Surface Science, 448. pp. 154-162. ISSN 0169-4332 DOI https://doi.org/10.1016/j.apsusc.2018.04.077
Guo, R. and Brigden, C.T. and Gin, S. and Swanton, S.W. and Farnan, I. (2018) The effect of magnesium on the local structure and initial dissolution rate of simplified UK Magnox waste glasses. Journal of Non-Crystalline Solids, 497. pp. 82-92. ISSN 00223093 DOI https://doi.org/10.1016/j.jnoncrysol.2018.03.002
Patel, Karishma B. and Boizot, Bruno and Facq, Sébastien P. and Peuget, Sylvain and Schuller, Sophie and Farnan, Ian (2017) Impacts of composition and beta irradiation on phase separation in multiphase amorphous calcium borosilicates. Journal of Non-Crystalline Solids, 473. pp. 1-16. ISSN 0022-3093 DOI https://doi.org/10.1016/j.jnoncrysol.2017.06.018
Iwalewa, Tajudeen M. and Qu, Tingyu and Farnan, Ian (2017) Investigation of the maximum dissolution rates and temperature dependence of a simulated UK nuclear waste glass in circum-neutral media at 40 and 90 ° C in a dynamic system. Applied Geochemistry, 82. pp. 177-190. ISSN 0883-2927 DOI https://doi.org/10.1016/j.apgeochem.2017.05.018
Patel, Karishma B. and Boizot, Bruno and Facq, Sébastien P. and Lampronti, Giulio I. and Peuget, Sylvain and Schuller, Sophie and Farnan, Ian (2017) β-Irradiation Effects on the Formation and Stability of CaMoO4 in a Soda Lime Borosilicate Glass Ceramic for Nuclear Waste Storage. Inorganic Chemistry, 56 (3). pp. 1558-1573. ISSN 0020-1669, ESSN: 1520-510X DOI https://doi.org/10.1021/acs.inorgchem.6b02657
Popel, A. J. and Le Solliec, S. and Lampronti, G. I. and Day, J. and Petrov, P. K. and Farnan, I. (2017) The effect of fission-energy Xe ion irradiation on the structural integrity and dissolution of the CeO2 matrix. Journal of Nuclear Materials, 484. pp. 332-338. ISSN 00223115 DOI https://doi.org/10.1016/j.jnucmat.2016.10.046
Roberts, J. and Gaugliardo, P. and Farnan, I. and Zhang, M. and Vance, E. R. and Davis, J. and Karatchevtseva, I. and Knott, R. B. and Mudie, S. and Buckman, S. J. and Sullivan, J. P. (2016) Positron annihilation lifetime study of radiation-damaged natural zircons. Journal of Nuclear Materials, 471. pp. 44-50. ISSN 0022-3115 DOI https://doi.org/10.1016/j.jnucmat.2015.12.008
Farnan, Ian and Berthon, Claude (2016) Applications of NMR in nuclear chemistry. In: Nuclear Magnetic Resonance. Royal Society of Chemistry, pp. 96-141. ISBN Print ISBN: 978-1-78262-053-2 PDF eISBN: 978-1-78262-410-3 EPUB eISBN: 978-1-78262-869-9
Popel, A. J. and Adamska, A.M. and Martin, P.G. and Payton, O.D. and Lampronti, G. I. and Picco, L. and Payne, L. and Springell, R. and Scott, T.B. and Monnet, I. and Grygiel, C. and Farnan, I. (2016) Structural effects in UO2 thin films irradiated with U ions. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 386. pp. 8-15. ISSN 0168583X DOI https://doi.org/10.1016/j.nimb.2016.09.019
Popel, A. J. and Lebedev, V.A. and Martin, P.G. and Shiryaev, A.A. and Lampronti, G. I. and Springell, R. and Kalmykov, S.N. and Scott, T.B. and Monnet, I. and Grygiel, C. and Farnan, I. (2016) Structural effects in UO2 thin films irradiated with fission-energy Xe ions. Journal of Nuclear Materials, 482. pp. 210-217. ISSN 0022-3115 DOI https://doi.org/10.1016/j.jnucmat.2016.10.024
Teterin, Yuri A. and Popel, Aleksej J. and Maslakov, Konstantin I. and Teterin, Anton Yu. and Ivanov, Kirill E. and Kalmykov, Stepan N. and Springell, Ross and Scott, Thomas B. and Farnan, Ian (2016) XPS Study of Ion Irradiated and Unirradiated UO2 Thin Films. Inorganic Chemistry. ISSN 0020-1669, ESSN: 1520-510X
Smye, Katie M. and Brigden, Clive and Vance, Eric R. and Farnan, Ian (2014) Quantification of α-particle radiation damage in zircon. American Mineralogist, 99 (10). pp. 2095-2104. ISSN 0003-004X DOI https://doi.org/10.2138/am-2014-4664
Martel, Laura and Magnani, Nicola and Vigier, Jean-Francois and Boshoven, Jacobus and Selfslag, Chris and Farnan, Ian and Griveau, Jean-Christophe and Somers, Joseph and Fanghänel, Thomas (2014) High-Resolution Solid-State Oxygen-17 NMR of Actinide-Bearing Compounds: An Insight into the 5f Chemistry. Inorganic Chemistry, 53 (13). pp. 6928-6933. ISSN 0020-1669, ESSN: 1520-510X DOI https://doi.org/10.1021/ic5007555
Vance, E. R. and Davis, J. and Olufson, K. and Gregg, D. J. and Blackford, M. G. and Griffiths, G. R. and Farnan, I. and Sullivan, J. and Sprouster, D. and Campbell, C. and Hughes, J. (2014) Leaching behaviour of and Cs disposition in a UMo powellite glass–ceramic. Journal of Nuclear Materials, 448 (1-3). pp. 325-329. ISSN 0022-3115 DOI https://doi.org/10.1016/j.jnucmat.2014.02.024
Carvajal Nuñez , R. and Prieur and Eloirdi, R. and Prieur, D. and Martel, L. and Lopez Honorato, E. and Farnan, I. and Vitova, T. and Somers, J. (2014) Structure of UC2 and U2C3:XRD, 13C NMR and EXAFS study. Journal of Alloys and Compounds, 589. pp. 234-239. ISSN ISSN: 0925-8388 DOI https://doi.org/10.1016/j.jallcom.2013.11.202
Smith, A. L. and Raison, P. E. and Martel, L. and Charpentier, T. and Farnan, I. and Prieur, D. and Hennig, C. and Scheinost, A. C. and Konings, R. J. M. and Cheetham, A. K. (2014) A 23Na Magic Angle Spinning Nuclear Magnetic Resonance, XANES, and High-Temperature X-ray Diffraction Study of NaUO3, Na4UO5, and Na2U2O7. Inorganic Chemistry, 53 (1). pp. 375-382. ISSN 0020-1669, ESSN: 1520-510X DOI https://doi.org/10.1021/ic402306c
Brigden, C. T. and Farnan, I. and Hania, P. R. (2014) Multi-nuclear NMR study of polytype and defect distribution in neutron irradiated silicon carbide. Journal of Nuclear Materials, 444 (1-3). pp. 92-100. ISSN 0022-3115 DOI https://doi.org/10.1016/j.jnucmat.2013.09.033
Carvajal Nuñez, U. and Martel, L. and Prieur, D. and Lopez Honorato, E. and Eloirdi, R. and Farnan, I. and Vitova, T. and Somers, J. (2013) Coupling XRD, EXAFS, and 13C NMR to Study the Effect of the Carbon Stoichiometry on the Local Structure of UC1±x. Inorganic Chemistry, 52 (19). pp. 11669-11676. ISSN 0020-1669, ESSN: 1520-510X DOI https://doi.org/10.1021/ic402144g
Rauff-Nisthar, Nadya and Boxall, Colin and Farnan, Ian and Hiezl, Zoltan and Lee, William and Perkins, Chris and Wilbraham, Richard J. (2013) Corrosion Behavior of AGR Simulated Fuels – Evolution of the Fuel Surface. ECS Transactions, 53 (21). pp. 95-104. ISSN 1938-6737, 1938-5862 DOI https://doi.org/10.1149/05321.0095ecst
López-Honorato, E. and Brigden, C. T. and Shatwell, R.A. and Zhang, H. and Farnan, I. and Xiao, P. and Guillermier, P. and Somers, J. (2013) Silicon carbide polytype characterisation in coated fuel particles by Raman spectroscopy and 29Si magic angle spinning NMR. Journal of Nuclear Materials, 433 (1-3). pp. 199-205. DOI https://doi.org/10.1016/j.jnucmat.2012.08.047
Blanc, Frédéric and Middlemiss, Derek S. and Buannic, Lucienne and Palumbo, John L. and Farnan, Ian and Grey, Clare P. (2012) Thermal phase transformations in LaGaO3 and LaAlO3 perovskites: An experimental and computational solid-state NMR study. Solid State Nuclear Magnetic Resonance, 42. pp. 87-97. ISSN 0926-2040 DOI https://doi.org/10.1016/j.ssnmr.2012.01.003
Vance, E. R. and Davies, J. and Olufson, K and Chironi, I. and Karatchevtseva, I. and Farnan, I. (2012) Candidate waste forms for immobilisation of waste chloride salt from pyroprocessing of spent nuclear fuel. Journal of Nuclear Materials, 420 (1–3). pp. 396-404. ISSN 0022-3115 DOI doi; 10.1016/j.jnucmat.2011.09.020
Xie, Xiaohu and Sun, Jialin and Brigden, C. T. and Farnan, Ian and Hong, Yanruo and Vasant Kumar, R. (2011) Understanding the relationship between dopant and ionic transport in yttria-doped ceria-zirconia. Journal of Materials Chemistry, 21 (26). p. 9570. DOI https://doi.org/10.1039/C1JM10884K
Brazhkin, V. V. and Farnan, I. and Funakoshi, Ken-ichi and Kanzaki, M. and Katayama, Y. and Lyapin, A. G. and Saitoh, H. (2010) Structural Transformations and Anomalous Viscosity in the B_{2}O_{3} Melt under High Pressure. Physical Review Letters, 105 (11). p. 115701. DOI https://doi.org/10.1103/PhysRevLett.105.115701
Darby, R.J. and Farnan, I. and Kumar, R.V. (2009) Method for making minor dopant additions to porous ceramics. Advances in Applied Ceramics, 108 (8). pp. 506-508. DOI https://doi.org/10.1179/174367609X459531
Zhang, M. and Ewing, R. C. and Boatner, L. A. and Salje, E. K. H. and Weber, W. J. and Daniel, P. and Zhang, Y. and Farnan, I. (2009) Pb+ irradiation of synthetic zircon (ZrSiO4): Infrared spectroscopic investigation--Reply. American Mineralogist, 94 (5-6). pp. 856-858. DOI https://doi.org/10.2138/am.2009.542
Kroeker, S. and Farnan, I. and Schuller, S. and Advocat, T. (2009) 95Mo NMR Study of Crystallization in Model Nuclear Waste Glasses. In: Materials Research Society Symposium Proceedings.
Darby, R. J. and Farnan, I. and Kumar, R. V. (2009) ΔThe effect of co-doping on the yttrium local environment and ionic conductivity of yttria-stabilised zirconia. Ionics, 15 (2). p. 183. ISSN 0947-7047 (Print) 1862-0760 (Online) DOI https://doi.org/10.1007/s11581-008-0250-z
Zhang, M. and Boatner, L. A. and Salje, E. K. H. and Ewing, R. C. and Daniel, P. and Weber, W. J. and Zhang, Y. and Farnan, Ian (2008) Micro-Raman and micro-infrared spectroscopic studies of Pb- and Au-irradiated ZrSiO[sub 4]: Optical properties, structural damage, and amorphization. Physical Review B (Condensed Matter and Materials Physics), 77 (14). pp. 144110-13. DOI https://doi.org/10.1103/PhysRevB.77.144110
Ashbrook, S. E. and Le Polles, L. and Pickard, C. J. and Berry, A. J. and Wimperis, S. and Farnan, I. (2007) First-principles calculations of solid-state 17O and 29Si NMR spectra of Mg2SiO4 polymorphs. Physical Chemistry Chemical Physics, 9 (13). pp. 1587-1598. DOI https://doi.org/10.1039/b618211a
Larsen, F. H. and Rossano, S. and Farnan, I. (2007) Order and disorder in titanosilicate glass by O-17 MAS, off-MAS, and 3Q-QCPMG-MAS solid-state NMR. Journal of Physical Chemistry B, 111 (28). pp. 8014-8019. ISSN 1520-6106 DOI https://doi.org/10.1021/jp071539n
Farnan, I. and Cho, H. and Weber, W. J. (2007) Quantification of actinide α-radiation damage in minerals and ceramics. Nature, 445 (7124). pp. 190-193. DOI https://doi.org/10.1038/nature05425
Whittle, K. R. and Ashbrook, S. E. and Lumpkin, G. R. and Farnan, I. and Smith, R. I. and Redfern, S. A. T. (2007) The effect of caesium on barium hollandites studied by neutron diffraction and magic-angle spinning (MAS) nuclear magnetic resonance. Journal of Materials Science, 42 (22). pp. 9379-9391. ISSN 0022-2461 (Print) 1573-4803 (Online) DOI https://doi.org/10.1007/s10853-007-1815-3
Nuttall, W. J. and Farnan, I. and Konings, R. J. M. and Hamilton, D. J. (2007) The management of separated plutonium: An introduction. Progress in Nuclear Energy, 49 (8). pp. 568-573. DOI https://doi.org/10.1016/j.pnucene.2007.09.002
Farnan, I. and Cho, H. and Weber, W. J. (2006) Identifying and quantifying actinide radiation damage in ZrSiO4 minerals and ceramics with nuclear magnetic resonance. In: Recent advances in actinide science. Special Publication, Royal society of Chemistry, 305 . Royal Society of Chemistry, Cambridge, pp. 305-310.
Larsen, F. H. and Farnan, I. and Lipton, A. S. (2006) Separation of Ti-47 and Ti-49 solid-state NMR lineshapes by static QCPMG experiments at multiple fields. Journal of Magnetic Resonance, 178 (2). pp. 228-236. DOI https://doi.org/10.1016/j.jmr.2005.10.003
Ashbrook, S. E. and Whittle, K. R. and Lumpkin, G. R. and Farnan, I. (2006) 89Y Magic-Angle Spinning NMR of Y2Ti2-xSnxO7 Pyrochlores. Journal of Physical Chemistry B, 110 (21). 10358 -10364. DOI https://doi.org/10.1021/jp060844q
Ashbrook, S. E. and Whittle, K. R. and Le Pollès, L. and Farnan, I. (2005) Disorder and dynamics in pollucite from 133Cs and 27Al NMR. Journal of the American Ceramic Society, 88 (6). pp. 1575-1583. DOI https://doi.org/10.1111/j.1551-2916.2005.00294.x
Pruneda, J. M. and Le Polles, L. and Farnan, I. and Trachenko, K. and Dove, M. T. and Artacho, E. (2005) Calculation of the effect of intrinsic point defects and volume swelling in the nuclear magnetic resonance spectra of ZrSiO4. Molecular Simulation, 31. pp. 349-354. DOI https://doi.org/10.1080/08927020500066916
Rossano, S. and Mauri, F. and Pickard, C. J. and Farnan, I. (2005) First-principles calculation of O-17 and Mg-25 NMR shieldings in MgO at finite temperature: Rovibrational effect in solids. Journal of Physical Chemistry B, 109. pp. 7245-7250. DOI https://doi.org/10.1021/jp044251w
